The ligand photolabilization of trans-[Fe(tim)-(CO)(MeCN)]2+(tim = 2,3,9,10-tetramethyl-1,4,8,11-tetra-azacyclotetradeca-1,3,8,10-tetraene) is controlled by the solvent with loss of CO occurring when the complex is photolysed in acetonitrile but loss of acetonitrile occurring when it is photolysed in acetone.
J. I. Zink and M. J. Incorvia, J. Chem. Soc., Chem. Commun., 1977, 730 DOI: 10.1039/C39770000730
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