A novel synthesis of (±)-prostaglandin-F2α involves the stereospecific formation of 3-endo-t-butyldimethylsiloxytricyclo[3.2.0.02,7]heptan-6-one (3) and reaction of this strained cyclopropyl ketone with the organocuprate reagent (4).
M. J. Dimsdale, R. F. Newton, D. K. Rainey, C. F. Webb, T. V. Lee and S. M. Roberts, J. Chem. Soc., Chem. Commun., 1977, 716 DOI: 10.1039/C39770000716
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