Investigation by deuterium-labelling of the isomerisation of dihydroxyalkyl radicals formed upon photolysis of cobaloxime complexes
Abstract
Anaerobic photolysis of 5-deuterio-4,5-dihydrooxyhexyl(pyridine)cobaloxime at pH 3 gives 2-deuteriohexanal and probably 6-deuteriohexan-2-one.