Sodium OO-diethyl phosphorotelluroate (1), which can be used as a stoicheiometric reagent or generated continuously in situ from a catalytic portion of Te, converts terminal epoxides efficiently into the corresponding olefins.
D. L. J. Clive and S. M. Menchen, J. Chem. Soc., Chem. Commun., 1977, 658 DOI: 10.1039/C39770000658
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