A short total synthesis of the sesquiterpene ishwarane has been achieved using, as the key step, carbon atom insertion with carbon tetrabromide and methyl-lithium to form the tricyclo[3.2.1.02,7]octane ring system of the natural product.
R. M. Cory and F. R. McLaren, J. Chem. Soc., Chem. Commun., 1977, 587 DOI: 10.1039/C39770000587
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