Issue 16, 1977

Background of the nuclear magnetic resonance antipodal shift induced by substituents; an analogy of the mesomeric effect with borane skeletons

Abstract

A range of substituents in those boranes or heteroboranes whose molecular structure is based on the icosahedron produce distinct n.m.r. chemical shifts at the cage atom antipodal to the point of substitution; such shifts can be correlated with the 13C chemical shift of the para-position in monosubstituted benzenes, and a parallelism, but not an identity, between ‘antipodal’ and ‘mesomeric’ effects is suggested.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 561-563

Background of the nuclear magnetic resonance antipodal shift induced by substituents; an analogy of the mesomeric effect with borane skeletons

S. Heřmánek, J. Plešek, V. Gregor and B. Štíbr, J. Chem. Soc., Chem. Commun., 1977, 561 DOI: 10.1039/C39770000561

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