α-Chloroethyltrimethylsilane (1) is deprotonated to give (2) which reacts with ketones and aldehydes to give α,β-epoxysilanes, useful precursors to methyl ketones.
F. Cooke and P. Magnus, J. Chem. Soc., Chem. Commun., 1977, 513 DOI: 10.1039/C39770000513
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