The hydrogenation of cyclohexene with halogeno-transition metal complexes supported on phosphine-modified silica carriers has been studied; these complexes are 2 to 4 orders of magnitude more active than their homogeneous counterparts.
K. Kochloefl, W. Liebelt and H. Knözinger, J. Chem. Soc., Chem. Commun., 1977, 510 DOI: 10.1039/C39770000510
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