[Rh(η5-C5Me5)Cl2]2 catalyses the hydrogenation of benzene and a variety of substituted benzenes to the appropriate cyclohexanes under homogeneous conditions (50 °C, 50 atm) in the presence of base (Et3N); the reaction is highly stereoselective and all-cis isomers are the chief products.
M. J. Russell, C. White and P. M. Maitlis, J. Chem. Soc., Chem. Commun., 1977, 427 DOI: 10.1039/C39770000427
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