Stereospecific formation of threo-1,2-dideuterio-2-chloroethanol [threo-(3)] in the Wacker reaction of trans-1,2-dideuterioethene (2) indicates that the hydroxy-palladation step is a trans-process.
Jan-E. Bäckvall, B. Åkermark and S. O. Ljunggren, J. Chem. Soc., Chem. Commun., 1977, 264 DOI: 10.1039/C39770000264
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