Issue 8, 1977

A new cationic S–N ring system, S4N42+. The crystal structure of cyclotetrathiazyl bis hexachloroantimonate(V), [S4N4][SbCl6]2, and cyclotetrathiazyl hexafluoroantimonate(V) tetradecafluorotriantimonate, [S4N4][SbF6][Sb3F14]

Abstract

An X-ray crystallographic study has shown that the new cyclic cation S4N42+ has different structures in the compounds [S4N4][SbCl6]2 and [S4N4][SbF6][Sb3F14] which were prepared by the reactions of S4N4 or S3N3Cl3 with SbCl5 and of S4N4 with SbF5, respectively.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 253-255

A new cationic S–N ring system, S4N42+. The crystal structure of cyclotetrathiazyl bis hexachloroantimonate(V), [S4N4][SbCl6]2, and cyclotetrathiazyl hexafluoroantimonate(V) tetradecafluorotriantimonate, [S4N4][SbF6][Sb3F14]

R. J. Gillespie, D. R. Slim and J. D. Tyrer, J. Chem. Soc., Chem. Commun., 1977, 253 DOI: 10.1039/C39770000253

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