The first example of a facially substituted dihalogeno-nido-decaborane(14), 5,10-B10H12Br2, has been obtained from the reaction of Br2 with Me2SnB10H12; its structure has been determined by X-ray crystallography.
R. E. Loffredo, T. J. Dupont, R. C. Haltiwanger and A. D. Norman, J. Chem. Soc., Chem. Commun., 1977, 121 DOI: 10.1039/C39770000121
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