Derivative (3) undergoes epimerisation at position 3 of its β-thiolactone ring when treated with triethylamine; alkylation occurs at the same site in the presence of a strong base and an alkylating agent.
S. D. Carter and R. J. Stoodley, J. Chem. Soc., Chem. Commun., 1977, 92 DOI: 10.1039/C39770000092
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