Newly synthesized trans-[PdCl2(R1R2C![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
N1–N2R3R4)2] complexes have a high Pd–N1 rotational barrier which, in solution, gives rise to two isomers depending on the relative orientations of the hydrazone molecules with respect to each other (symmetrical in one isomer and asymmetrical in the other).
G. Natile, L. Cattalini and F. Gasparrini, J. Chem. Soc., Chem. Commun., 1977, 89 DOI: 10.1039/C39770000089
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