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Issue 22, 1977
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Mechanism of the fluxional behaviour in (1–5-η-cycloheptadienyl)-(1–5-η-cycloheptatrienyl)iron

Abstract

Evidence for a 1,2-shift mechanism of the 1–5-η-cycloheptatrienyl moiety with respect to the central iron atom of the title compound is presented together with absolute assignments of the 13C n.m.r. chemical shifts of the C7H7 ring. A low-temperature rocking motion of both rings can be frozen out at –70 °C.

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Article information


J. Chem. Soc., Dalton Trans., 1977, 2205-2209
Article type
Paper

Mechanism of the fluxional behaviour in (1–5-η-cycloheptadienyl)-(1–5-η-cycloheptatrienyl)iron

J. R. Blackborow, R. H. Grubbs, K. Hildenbrand, E. A. K. von Gustorf, A. Miyashita and A. Scrivanti, J. Chem. Soc., Dalton Trans., 1977, 2205 DOI: 10.1039/DT9770002205

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