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Issue 18, 1977
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Initiation of olefin metathesis: reaction of deca-2,8-diene with catalysts formed from Me4Sn–WCl6 and Me3Al2Cl3–(Ph3P)2(NO)2Cl2Mo

Abstract

The initial product of the metathesis of deca-2,8-diene with metathesis catalysts formed from either Me4Sn–WCl6 or Me3Al2Cl3–(Ph3P)2(NO)2Cl2Mo is propene; labelling of the terminal groups of the diene and the alkylating agents gives a labelling pattern in the propene that is best explained in terms of generation of a carbene in the initiation step from the alkylating agent.

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Article information


J. Chem. Soc., Chem. Commun., 1977, 634-635
Article type
Paper

Initiation of olefin metathesis: reaction of deca-2,8-diene with catalysts formed from Me4Sn–WCl6 and Me3Al2Cl3–(Ph3P)2(NO)2Cl2Mo

R. H. Grubbs and C. R. Hoppin, J. Chem. Soc., Chem. Commun., 1977, 634 DOI: 10.1039/C39770000634

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