Issue 8, 1976

Substituent effects in five-membered rings: σHet constants for thia- and oxa-substituents from the reaction of arenesulphonyl chlorides with aniline

Abstract

σHet Values for thia- and oxa-substituents in five-membered heterocycles are derived from the rate constants for the reactions of suiphonyl chlorides with aniline in methanol. These values, which are negative and similar to σ+, are in agreement with the SAN mechanism previously proposed.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1976, 906-908

Substituent effects in five-membered rings: σHet constants for thia- and oxa-substituents from the reaction of arenesulphonyl chlorides with aniline

E. Maccarone, G. Musumarra and G. A. Tomaselli, J. Chem. Soc., Perkin Trans. 2, 1976, 906 DOI: 10.1039/P29760000906

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