The e.s.r. spectra of methyl radicals bearing alkoxy-, alkylthio-, or chloro-substituents are reported. The coupling constants are discussed in terms of non-planarity of the radical centre.
E. A. C. Lucken and B. Poncioni, J. Chem. Soc., Perkin Trans. 2, 1976, 777 DOI: 10.1039/P29760000777
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