An n.m.r. study of barriers to rotation and conformational equilibria in 2-halogeno-2, 3, 3-trimethylbutanes and 2-halogeno-2, 3-dimethylbutanes is reported. Results are discussed in terms of the steric requirement of halogen atoms, and the interaction of these atoms with adjacent methyl groups.
J. E. Anderson, C. W. Doecke and H. Pearson, J. Chem. Soc., Perkin Trans. 2, 1976, 336 DOI: 10.1039/P29760000336
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