Participation of a vicinal trans-axial acetoxy-group in the boron trifluoride-catalysed cleavage of steroidal epoxides, resulting in some cases in overall diequatorial opening of the oxiran ring, is described.
T. H. Campion, G. A. Morrison and J. B. Wilkinson, J. Chem. Soc., Perkin Trans. 1, 1976, 2508 DOI: 10.1039/P19760002508
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