Bromination of the title diazepine (1) in chloroform gives 2-bromomethyl-4-methyl-1,5-benzodiazepinium bromide (5), whereas bromination in glacial acetic acid gives 2,4-bis(dibromomethyl)-1,5-benzodiazepinium bromide (6) and 3,7,8-tribromo-2,4-bis(tribromomethyl)-1,5-benzodiazepine (12).
R. L. Williams, W. Peaston and J. Kern, J. Chem. Soc., Perkin Trans. 1, 1976, 2353 DOI: 10.1039/P19760002353
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