Calculations of frequencies of “out of plane” atomic vibrations from a very approximate model indicate that the relaxation mechanism of dielectric loss in compounds like metal acetylacetonates and disiloxanes may involve this type of movement.
S. Dasgupta, J. Chem. Soc., Faraday Trans. 2, 1976, 72, 1716 DOI: 10.1039/F29767201716
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