It is shown that the formation of CO and CH4 in the argon-sensitized γ-radiolysis of methanol is dependent on a mechanism of charge exchange with the species Ar+. On the other hand, the ion Ar+2 formed from Ar* is of minor importance. The formation of CH+3 from methanol after charge exchange with Ar+ is a rapid process, taking about 10–13s.
B. Jonsson and J. Lind, J. Chem. Soc., Faraday Trans. 2, 1976, 72, 906 DOI: 10.1039/F29767200906
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