Issue 0, 1976
From the journal:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

Reactions of chlorine oxide radicals. Part 6.—The reaction O + ClO → Cl + O2 from 220 to 426 K

Michael A. A. Clyne  and  Wing S. Nip  

Abstract

The rate constant k1 for the reaction O3PJ+ ClO → Cl 2PJ+ O2 has been measured at five temperatures between 220 and 426 K. Atomic resonance fluorescence was used to follow the pseudo-first order decay rate of [O 3PJ] in excess ClO, which was produced by the reaction Cl + O3→ ClO + O2. The following Arrhenius expression for k1(cm3 molecule–1 s–1; 220–426 K; 2σ) is reported: log10k1=(– 9.97 ± 0.12)–(97.2 ± 32.8)/T.

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Article information

DOI
https://doi.org/10.1039/F19767202211
Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1976,72, 2211-2217

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Reactions of chlorine oxide radicals. Part 6.—The reaction O + ClO → Cl + O2 from 220 to 426 K

M. A. A. Clyne and W. S. Nip, J. Chem. Soc., Faraday Trans. 1, 1976, 72, 2211 DOI: 10.1039/F19767202211

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