Investigation of the kinetics of the abstraction of primary and tertiary hydrogen atoms by chlorine atoms indicates that the presence of an inert gas (hexafluoroethane) has a marginal effect. Improved Arrhenius parameters have been derived for these reactions and parameters found for the fluoroethanes.
P. Cadman, A. W. Kirk and A. F. Trotman-Dickenson, J. Chem. Soc., Faraday Trans. 1, 1976, 72, 1027 DOI: 10.1039/F19767201027
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