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Issue 20, 1976
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Reaction of higher dialkyl(methylthio)boranes with bromine: a new synthesis of dialkylbromoboranes

Abstract

Higher dialkyl(methylthio)boranes, readily prepared in situ from the corresponding trialkylboranes, react rapidly at low temperature with bromine to give dialkylbromoboranes and dimethyl disulphide. Removal of the latter under reduced pressure gives a pure product in excellent yield.

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Article information


J. Chem. Soc., Dalton Trans., 1976, 2087-2090
Article type
Paper

Reaction of higher dialkyl(methylthio)boranes with bromine: a new synthesis of dialkylbromoboranes

A. Pelter, K. Rowe, D. N. Sharrocks, K. Smith and C. Subrahmanyam, J. Chem. Soc., Dalton Trans., 1976, 2087
DOI: 10.1039/DT9760002087

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