The monomer–dimer equilibrium in solutions of chromium(II) acetate has been investigated by spectrophotometric and solubility measurements. The principal dimeric species in solution is [Cr2(O2CMe)4]. The equilibrium constant for [Cr2(O2CMe)2]⇌ 2Cr(O2CMe)2 is log KDO=–4.35, and for Cr2++ 2MeCO2–⇌ Cr(O2CMe)2 is log β2= 1.70, at 25 °C and ionic strength 1.0 mol dm–3(Na[ClO4]).
R. D. Cannon and M. J. Gholami, J. Chem. Soc., Dalton Trans., 1976, 1574 DOI: 10.1039/DT9760001574
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...