Kinetics of metal-ion-catalysed aquation of the hexachlororhenate(IV) and hexabromorhenate(IV) anions in aqueous solution
Abstract
Kinetic parameters are reported for catalysis of the aquation of the hexachlororhenate(IV) anion by mercury(II), thallium(III), cadmium(II), and indium(III), and of the hexabromorhenate(IV) anion by thallium(III), in aqueous solution. Correlation of these kinetic results with stability constants for halogeno-complexes of the respective metal cations is discussed.
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