The complex [N(PPh3)2][Fe(CO)3(NO)] reacts with alkyl halides to afford [N(PPh3)2][FeX2(NO)2](X = Cl, Br, or I) and with halogens to afford [N(PPh3)2][FeX3(NO)](X = Cl or Br) and [N(PPh3)2][FeI2(NO)2]. The relations between the two sets of paramagnetic anions, their reactivity, and their magnetic and e.s.r. spectral properties are discussed.
N. G. Connelly and C. Gardner, J. Chem. Soc., Dalton Trans., 1976, 1525 DOI: 10.1039/DT9760001525
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