A 19F n.m.r. study of the reactions of [TiF5]– with neutral Lewis bases is reported. The factors which contribute to the formation of [TiF5]–·D complexes are considered. Fluorine-19 n.m.r. data for over 30 complexes are presented and the effects of donor basicity, pπ–dπ bonding, and solvent interactions on the chemical shifts are discussed.
H. G. Lee, D. S. Dyer and R. O. Ragsdale, J. Chem. Soc., Dalton Trans., 1976, 1325 DOI: 10.1039/DT9760001325
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