[Ru(NO)2(PPh3)2] reacts with PhCH2Br in hot toluene under CO to give [RuBr(CO)(NO)(PPh3)2], [RuBr2(CO)2(PPh3)2], PhCh![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
NOH, PhCN, and PhCONH2, together with small amounts of PhCHO and PhCH2OH; in the absence of CO, under N2 or C2H4, the yields of organonitrogen products are reduced, and [RuBr2(NCPh)2(PPh3)2] and [RuBr3(NO)(PPh3)2] are formed.
J. A. McCleverty, C. W. Ninnes and I. Wołochowicz, J. Chem. Soc., Chem. Commun., 1976, 1061 DOI: 10.1039/C39760001061
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