η 3 Cyclohepta-2,4-dienylpalladium complex are fluxional in solution owing to intercharge of C(1) and C(5), C(2) and C(4), and C(6) and C(7); a 1,3-shift mechanism is indicatred for the interchanges and there is a direct relation between ΔG‡ and the trans-effectiveness of L in [Pd(C7H9)L2] or [Pd(C7H9)L2]PF6.
B. E. Mann and P. M. Maitlis, J. Chem. Soc., Chem. Commun., 1976, 1058 DOI: 10.1039/C39760001058
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