Treatment of aromatic hydrocarbons with nitromethane and manganese(III) acetate produces aryl nitromethanes by way of homolytic aromatic substitution involving the ·CH2NO2 radical.
M. E. Kurz and R. T. Y. Chen, J. Chem. Soc., Chem. Commun., 1976, 968 DOI: 10.1039/C39760000968
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