Issue 22, 1976

Preparation of ferrocenium phosphorus, arsenic, antimony, and bismuth halides. The structure of ferrocenium tetrachlorobismuthate

Abstract

Eleven ferrocenium halogenopentelides (P, As, Sb, or Bi) have been prepared by the reaction of a group 5 element halide with ferrocene in an organic solvent; the structure of one of the products, [Fe(η5-C5H5)2][BiCl4], determined by X-ray crystallography, reveals an extended, one-dimensional anion of irregular, edgesharing BiCl63– octahedra.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 931-932

Preparation of ferrocenium phosphorus, arsenic, antimony, and bismuth halides. The structure of ferrocenium tetrachlorobismuthate

A. G. Landers, M. W. Lynch, S. B. Raaberg, A. L. Rheingold, J. E. Lewis, N. J. Mammano and A. Zalkin, J. Chem. Soc., Chem. Commun., 1976, 931 DOI: 10.1039/C39760000931

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