[H2Ru(PPh3)4] catalyses the [2+2] cross-addition of norbornene derivatives and dimethyl acetylenedicarboxylate to give exo-tricyclo[4.2.1.02,5]nonenes.
T. Mitsudo, K. Kokuryo and Y. Takegami, J. Chem. Soc., Chem. Commun., 1976, 722 DOI: 10.1039/C39760000722
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