Reaction of 2-chlorotropone with an excess of an alkoxide in dimethyl sulphoxide gives the gem-dialkoxy adduct (2) which on neutralization affords 2-alkoxytropone, failure only occurring for very bulky alkoxides.
R. Cabrino, M. Cavazza and F. Pietra, J. Chem. Soc., Chem. Commun., 1976, 721 DOI: 10.1039/C39760000721
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