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Di-t-butyl ketone and 5,5,7,7-tetramethylunde-can-6-one have been found to isomerize slowly under strongly basic conditions (ButO––ButOH, 185 °C), constituting the first examples of skeletal rearrangement through β-enolizable (homoenolizable) methyl groups.
M. B. Rampersad and J. B. Stothers, J. Chem. Soc., Chem. Commun., 1976, 709 DOI: 10.1039/C39760000709
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