Suitably substituted arenediazonium salts undergo photolysis in a polymer film at 77 K to yield e.s.r. spectra characteristic of triplet states which are assigned to the corresponding aryl cations of configuration (π)5(sp2)1.
A. Cox, T. J. Kemp, D. R. Payne, M. C. R. Symons, D. M. Allen and P. P. de Moira, J. Chem. Soc., Chem. Commun., 1976, 693 DOI: 10.1039/C39760000693
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