Demethylhomopterocarpin (1) and vestitol (8) are interconvertible in CuCl2-treated lucerne seedings, but they appear to be synthesised simultaneously from a common intermediate; sativan (9) is probably derived by the methylation of vestitol.
P. M. Dewick and M. Martin, J. Chem. Soc., Chem. Commun., 1976, 637 DOI: 10.1039/C39760000637
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