The cyanide carbon atom in kinamycin D (1) was proved to originate from the acetate carboxy-carbon atom by 13C isotope shifts in the i.r. spectra of kinamycin D prepared from 95% enriched sodium [1-13C]acetate.
K. Ajisaka, H. Takeshima and S. Ōmura, J. Chem. Soc., Chem. Commun., 1976, 571 DOI: 10.1039/C39760000571
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