Treatment of sulphinamides with alcohols in the presence of strong acids results in the formation of sulphinates in good yields; this reaction has been shown to proceed with inversion of configuration at the sulphinyl centre and high stereospecificity which is dependent on the structure of the alcohol used.
M. Mikołajczyk, J. Drabowicz and B. Bujnicki, J. Chem. Soc., Chem. Commun., 1976, 568 DOI: 10.1039/C39760000568
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