Crystal and molecular structure of the five-co-ordinate, S
1, macrocyclic complex of cobalt(III), [Co(C22H22N4)I]·CHCl3: 7,16-dihydro-6,8,15,17-tetramethyldibenzo[b,i][1,4,8,11]tetra-azacyclotetradecinato(iodo)cobalt(III) iodide
Abstract
The X-ray crystal structure and its implications in chemical reactivity of a novel five-co-ordinate macrocyclic complex of cobalt(III), [Co(C22H22N4)I]·CHCl3, having an S= 1 ground state are described.
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1, macrocyclic complex of cobalt(III), [Co(C22H22N4)I]·CHCl3: 7,16-dihydro-6,8,15,17-tetramethyldibenzo[b,i][1,4,8,11]tetra-azacyclotetradecinato(iodo)cobalt(III) iodide