Perfluoro-(1,2-dialkylcyclopentenes), conveniently prepared by the co-oligomerisation of a perfluoroalkene and perfluorocyclopentene, and photolysed in the liquid phase, undergo a 1,3-allylic shift to give the isomeric perfluoro-(1-alkenyl-1-alkylcyclopropanes) in high yield.
J. V. Drayton (<em xmlns="http://www.rsc.org/schema/rscart38">née</em> Worthington), W. T. Flowers, R. N. Haszeldine and T. A. Parry, J. Chem. Soc., Chem. Commun., 1976, 490 DOI: 10.1039/C39760000490
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