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Issue 11, 1976
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Direct formation, and reactions of a carbonyl anion free from competitive nucleophiles

Abstract

At low temperature, in tetrahydrofuran (THF)–ether-pentane, ButLi abstracts a proton from bis(isopropyl)formamide to give LiCONPri2, which reacts with carbonyl compounds to give high yields of α-hydroxyamides.

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Article information


J. Chem. Soc., Chem. Commun., 1976, 387-388
Article type
Paper

Direct formation, and reactions of a carbonyl anion free from competitive nucleophiles

K. Smith and K. Swaminathan, J. Chem. Soc., Chem. Commun., 1976, 387
DOI: 10.1039/C39760000387

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