Formic acid-catalysed rearrangement of carotol (1) gives, among other products, the alcohol (4); X-ray crystal structure determination of its p-iodobenzoate (7) showed that the ester contained enantiomeric forms of (4).
L. H. Zalkow, M. G. Clower, M. G. J. Smith, D. VanDerveer and J. A. Bertrand, J. Chem. Soc., Chem. Commun., 1976, 374 DOI: 10.1039/C39760000374
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