It is shown that protonated acetone undergoes a rate-determining isomerisation onto the same potential surface as protonated propionaldehyde prior to unimolecular decomposition.
G. Hvistendahl, R. D. Bowen and D. H. Williams, J. Chem. Soc., Chem. Commun., 1976, 294 DOI: 10.1039/C39760000294
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