Optically stable thiosulphinate S-esters containing the t-butylthio-group have been prepared by the asymmetric condensation of sulphinyl chlorides with achiral thiols in the presence of optically active tertiary amines; they have been converted into sulphoxides, sulphinamides, and sulphinates.
M. Mikołajczyk and J. Drabowicz, J. Chem. Soc., Chem. Commun., 1976, 220 DOI: 10.1039/C39760000220
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