Cleavage of the complex (–)-[(π-MeCp)Mn(CO)2(H)SiMePh(α-Np)] by electrophiles and nucleophiles may occur in three ways: electrophilic cleavage of the Mn–Si bond with retention of configuration at Si, nucleophilic attack at Mn also with retention of configuration, and nucleophilic attack at Si with inversion of configuration.
E. Colomer, R. Corriu and A. Vioux, J. Chem. Soc., Chem. Commun., 1976, 175 DOI: 10.1039/C39760000175
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