The absorption of u.v. light by chiral oxaziridines having a stable pyramidal nitrogen configuration results in photoracemization via a mechanism involving C–O bond cleavage and a nitrone intermediate.
J. Bjørgo, D. R. Boyd, R. M. Campbell and D. C. Neill, J. Chem. Soc., Chem. Commun., 1976, 162 DOI: 10.1039/C39760000162
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