Phloracetophenone and phloroglucinaldehyde each give two isomeric citrans [(3) and (6)(8:1), and (4) and (7)(6:1)] respectively on heating (110 °C) with citral in pyridine; the structures of the major isomers (3) and (4) have been established by X-ray methods.
M. J. Begley, L. Crombie, R. W. King, D. A. Slack and D. A. Whiting, J. Chem. Soc., Chem. Commun., 1976, 138 DOI: 10.1039/C39760000138
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